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Williams |
The discovery of
oxygen was the last but most important blow to the tottering phlogiston
theory, though Priestley himself would not admit it. But before considering
the final steps in the overthrow of Stahl's famous theory and the establishment
of modern chemistry, we must review the work of another great chemist,
Karl Wilhelm Scheele (1742-1786), of Sweden, who discovered oxygen quite
independently, although later than Priestley. In the matter of brilliant
discoveries in a brief space of time Scheele probably eclipsed all his
great contemporaries. He had a veritable genius for interpreting chemical
reactions and discovering new substances, in this respect rivalling Priestley
himself. Unlike Priestley, however, he planned all his experiments along
the lines of definite theories from the beginning, the results obtained
being the logical outcome of a predetermined plan.
Scheele was the son of a merchant of Stralsund ,
Pomerania, which then belonged to Sweden. As a boy in school he showed
so little aptitude for the study of languages that he was apprenticed to
an apothecary at the age of fourteen. In this work he became at once greatly
interested, and, when not attending to his duties in the dispensary, he
was busy day and night making experiments or studying books on chemistry.
In 1775, still employed as an apothecary, he moved to Stockholm, and soon
after he sent to Bergman, the leading chemist of Sweden, his first discovery
- that of tartaric acid, which he had isolated from cream of tartar. This
was the beginning of his career of discovery, and from that time on until
his death he sent forth accounts of new discoveries almost uninterruptedly.
Meanwhile he was performing the duties of an ordinary apothecary, and struggling
against poverty. His treatise upon Air and Fire appeared in 1777. In this
remarkable book he tells of his discovery of oxygen - "empyreal" or "fire-air,"
as he calls it - which he seems to have made independently and without
ever having heard of the previous discovery by Priestley. In this book,
also, he shows that air is composed chiefly of oxygen and nitrogen gas.
Early in his experimental career Scheele
undertook the solution of the composition of black oxide of manganese,
a substance that had long puzzled the chemists. He not only succeeded in
this, but incidentally in the course of this series of experiments he discovered
oxygen, baryta, and chlorine, the last of far greater importance, at least
commercially, than the real object of his search. In speaking of the experiment
in which the discovery was made he says:
"When marine (hydrochloric) acid stood
over manganese in the cold it acquired a dark reddish-brown color. As manganese
does not give any colorless solution without uniting with phlogiston [probably
meaning hydrogen], it follows that marine acid can dissolve it without
this principle. But such a solution has a blue or red color. The color
is here more brown than red, the reason being that the very finest portions
of the manganese, which do not sink so easily, swim in the red solution;
for without these fine particles the solution is red, and red mixed with
black is brown. The manganese has here attached itself so loosely to acidum
salis that the water can precipitate it, and this precipitate behaves like
ordinary manganese. When, now, the mixture of manganese and spiritus salis
was set to digest, there arose an effervescence and smell of aqua regis."[6]
The "effervescence" he refers to was chlorine,
which he proceeded to confine in a suitable vessel and examine more fully.
He described it as having a "quite characteristically suffocating smell,"
which was very offensive. He very soon noted the decolorizing or bleaching
effects of this now product, finding that it decolorized flowers, vegetables,
and many other substances.
Commercially this discovery of chlorine
was of enormous importance, and the practical application of this new chemical
in bleaching cloth soon supplanted the, old process of crofting - that
is, bleaching by spreading the cloth upon the grass. But although Scheele
first pointed out the bleaching quality of his newly discovered gas, it
was the French savant, Berthollet, who, acting upon Scheele's discovery
that the new gas would decolorize vegetables and flowers, was led to suspect
that this property might be turned to account in destroying the color of
cloth. In 1785 he read a paper before the Academy of Sciences of Paris,
in which he showed that bleaching by chlorine was entirely satisfactory,
the color but not the substance of the cloth being affected. He had experimented
previously and found that the chlorine gas was soluble in water and could
thus be made practically available for bleaching purposes. In 1786 James
Watt examined specimens of the bleached cloth made by Berthollet, and upon
his return to England first instituted the process of practical bleaching.
His process, however, was not entirely satisfactory, and, after undergoing
various modifications and improvements, it was finally made thoroughly
practicable by Mr. Tennant, who hit upon a compound of chlorine and lime
- the chloride of lime - which was a comparatively cheap chemical product,
and answered the purpose better even than chlorine itself.
To appreciate how momentous this discovery
was to cloth manufacturers, it should be remembered that the old process
of bleaching consumed an entire summer for the whitening of a single piece
of linen; the new process reduced the period to a few hours. To be sure,
lime had been used with fair success previous to Tennant's discovery, but
successful and practical bleaching by a solution of chloride of lime was
first made possible by him and through Scheele's discovery of chlorine.
Until the time of Scheele the great subject
of organic chemistry had remained practically unexplored, but under the
touch of his marvellous inventive genius new methods of isolating and studying
animal and vegetable products were introduced, and a large number of acids
and other organic compounds prepared that had been hitherto unknown. His
explanations of chemical phenomena were based on the phlogiston theory,
in which, like Priestley, he always, believed. Although in error in this
respect, he was, nevertheless, able to make his discoveries with extremely
accurate interpretations. A brief epitome of the list of some of his more
important discoveries conveys some idea, of his fertility of mind as well
as his industry. In 1780 he discovered lactic acid,[7] and showed that
it was the substance that caused the acidity of sour milk; and in the same
year he discovered mucic acid. Next followed the discovery of tungstic
acid, and in 1783 he added to his list of useful discoveries that of glycerine.
Then in rapid succession came his announcements of the new vegetable products
citric, malic, oxalic, and gallic acids. Scheele not only made the discoveries,
but told the world how he had made them - how any chemist might have made
them if he chose - for he never considered that he had really discovered
any substance until he had made it, decomposed it, and made it again.
His experiments on Prussian blue are most
interesting, not only because of the enormous amount of work involved and
the skill he displayed in his experiments, but because all the time the
chemist was handling, smelling, and even tasting a compound of one of the
most deadly poisons, ignorant of the fact that the substance was a dangerous
one to handle. His escape from injury seems almost miraculous; for his
experiments, which were most elaborate, extended over a considerable period
of time, during which he seems to have handled this chemical with impunity.
While only forty years of age and just
at the zenith of his fame, Scheele was stricken by a fatal illness, probably
induced by his ceaseless labor and exposure. It is gratifying to know,
however, that during the last eight or nine years of his life he had been
less bound down by pecuniary difficulties than before, as Bergman had obtained
for him an annual grant from the Academy. But it was characteristic of
the man that, while devoting one-sixth of the amount of this grant to his
personal wants, the remaining five-sixths was devoted to the expense of
his experiments. |
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